Self-consistent model of hydrogen chemisorption. Computational screening of doped graphene electrodes for alkaline CO 2 reduction. Facile electron transfer to CO 2 during adsorption at the metal|solution interface. Dipole-field interactions determine the CO 2 reduction activity of 2D Fe–N–C single atom catalysts. Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on gold. Driving force dependence of inner-sphere electron transfer for the reduction of CO 2 on a gold electrode. Mechanism of the electrochemical reduction of carbon dioxide at inert electrodes in media of low proton availability. Proton-coupled electron transfer in the electrocatalysis of CO 2 reduction: prediction of sequential vs. Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels. Unraveling mechanistic reaction pathways of the electrochemical CO 2 reduction on Fe–N–C single-site catalysts. Electron transfer limitation in carbon dioxide reduction revealed by data-driven Tafel analysis. Electrocatalytic process of CO selectivity in electrochemical reduction of CO 2 at metal electrodes in aqueous media. Bayesian data analysis reveals no preference for cardinal Tafel slopes in CO 2 reduction electrocatalysis. Electric field effects in electrochemical CO 2 reduction. Understanding trends in the electrocatalytic activity of metals and enzymes for CO 2 reduction to CO. The central role of bicarbonate in the electrochemical reduction of carbon dioxide on gold. Stability and redispersion of Ni nanoparticles supported on N-doped carbons for the CO 2 electrochemical reduction. Insights into the low overpotential electroreduction of CO 2 to CO on a supported gold catalyst in an alkaline flow electrolyzer. Inhibited proton transfer enhances Au-catalyzed CO 2 -to-fuels selectivity. Wuttig, A., Yaguchi, M., Motobayashi, K., Osawa, M. pH effects on the selectivity of the electrocatalytic CO 2 reduction on graphene-embedded Fe–N–C motifs: bridging concepts between molecular homogeneous and solid-state heterogeneous catalysis. Influence of atomic surface structure on the activity of Ag for the electrochemical reduction of CO 2 to CO. Single site porphyrine-like structures advantages over metals for selective electrochemical CO 2 reduction. Technical photosynthesis involving CO 2 electrolysis and fermentation. Haas, T., Krause, R., Weber, R., Demler, M. Progress and perspectives of electrochemical CO 2 reduction on copper in aqueous electrolyte. Electrocatalytic synthesis of organic carbonates. Combining theory and experiment in electrocatalysis: insights into materials design. General techno-economic analysis of CO 2 electrolysis systems. We show that the increased activity of MNC catalysts is due to the stabilization of larger adsorbate dipoles, which results from their discrete and narrow d states. We present a unified activity volcano that includes the decisive CO 2* and COOH* binding strengths. We evaluate these computed mechanisms against pH-dependent experimental activity measurements on the CO 2R to CO activity. We find CO 2* adsorption to generally be limiting on TMs, whereas MNCs can be limited by either CO 2* adsorption or by the proton–electron transfer reaction to form COOH*. Applying the Newns–Andersen model, we find that on MNCs, like TMs, electron transfer to CO 2 is facile. Here we investigate the activity of transition metals (TMs), metal–nitrogen-doped carbon catalysts (MNCs) and a supported phthalocyanine, and present a unified mechanistic picture of the CO 2R to CO for these catalysts. The decomposition of the representations is again given by the Clebsch–Gordan coefficients, this time in the general Lie-algebra setting.CO is the simplest product from CO 2 electroreduction (CO 2R), but the identity and nature of its rate-limiting step remain controversial. Charges are often denoted by the letter Q, and so the invariance of the charge corresponds to the vanishing commutator = 0 being the Littlewood–Richardson coefficients. Charges correspond to the time-invariant generators of a symmetry group, and specifically, to the generators that commute with the Hamiltonian. In physics, a charge is any of many different quantities, such as the electric charge in electromagnetism or the color charge in quantum chromodynamics. JSTOR ( October 2015) ( Learn how and when to remove this template message).Unsourced material may be challenged and removed. Please help improve this article by adding citations to reliable sources. This article needs additional citations for verification.

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